FWIW, I snagged that table I posted above from Blue Sea![]()
Blue sea also has an ABYC table which is a helpful as it shows the derating based on the insulation temperature rating and environmental conditions.
http://assets.bluesea.com/files/resources/reference/21731.pdf
With that in mind, even if you could technically use a single strand of 2/0 wire with 105C insulation, you'll find things get a lot less toasty with 4/0.
Even my 4/0 wire gets quite hot when running a full load on my 3000w inverter.

